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Nickel Complexes with Two Types of Noninnocent Ligands: α‑Diimine and Phenazine

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NIAID Data Ecosystem2026-03-07 收录
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https://figshare.com/articles/dataset/Nickel_Complexes_with_Two_Types_of_Noninnocent_Ligands_Diimine_and_Phenazine/2415946
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The α-diimine nickel dibromo complex LNiBr2 (L = [(2,6-iPr2C6H3)­NC­(Me)]2) reacts with various amounts of potassium metal and phenazine (Phz) to afford the complexes [LNi­(η4-C4-Phz)] (1) and [K­(DME)]2[(LNi)2(μ-η1:η1-N,N-Phz)] (2), in which the Phz molecule adopts significantly different coordination modes with different oxidation states of Phz, Ni, and L.
创建时间:
2013-05-13
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