Nickel Complexes with Two Types of Noninnocent Ligands: α‑Diimine and Phenazine
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https://figshare.com/articles/dataset/Nickel_Complexes_with_Two_Types_of_Noninnocent_Ligands_Diimine_and_Phenazine/2415946
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资源简介:
The
α-diimine nickel dibromo complex LNiBr2 (L
= [(2,6-iPr2C6H3)NC(Me)]2) reacts with various amounts of potassium metal
and phenazine (Phz) to afford the complexes [LNi(η4-C4-Phz)]
(1) and [K(DME)]2[(LNi)2(μ-η1:η1-N,N-Phz)] (2), in which
the Phz molecule adopts significantly different coordination modes
with different oxidation states of Phz, Ni, and L.
创建时间:
2013-05-13



