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Directing Group Assisted Copper-Catalyzed Chemoselective <i>O</i>‑Aroylation of Phenols and Enols Using Alkylbenzenes

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NIAID Data Ecosystem2026-03-07 收录
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By using alkylbenzenes as aroyl surrogates, copper(II) catalyzed chemoselective O-aroylations of 1,3-dicarbonyl compounds and phenolic −OH ortho to carbonyl (−CHO, −COR) groups have been achieved. A dual mechanism operating in tandem for these transformations has been supported by a crossover experiment.

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2016-02-19
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