The reactivity of a series of disilazido zirconocene complexes is dominated by the migration of anionic groups (hydrogen, alkyl, halide, OTf) between the zirconium and silicon centers. The direction o
Understanding the formation of benzosiloles by the intramolecular palladium-catalyzed annulation of alkynyl(aryl)silanes is crucial for achieving synthetic diversity toward the enhancement of the ch
By means of Sonogashira reaction, a series of 2-alkynyl- and 2,7-dialkynyl derivatives of 1,8-bis(dimethylamino)naphthalene (“proton sponge”) have been obtained from the corresponding iodides. It w
The oxidative addition of PhX (X = I, Br, Cl) to the complexes Pd(PtBu3)2 (1), Pd(1-AdPtBu2)2 (2), Pd(CyPtBu2)2 (3), and Pd(PCy3)2 (4) (1-Ad = 1-adamantyl, Cy = cyclohexyl) was studied to determine th
