First Three-Dimensional Self-Penetrating Coordination Polymer Containing Rare (10,3)‑d Subnets: Synthesis, Structure, and Properties
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Hydrothermal assembly of ZnII ion, a tripodal ligand with both flexible imidazole and rigid carboxylate groups [HL = 3,5-bis(imidazol-1-ylmethyl)benzoic acid hydrochloride], and rigid bidentate linker 5-iodoisophthalic acid (5-iipa) yields a novel three-dimensional (3D) self-penetrating metal–organic framework [Zn2(L)2(5-iipa)]n (1). Complex 1 exhibits a (62·8)(63·8·102) topology that is unprecedented with the rare (10,3)-d (or utp) subnets. In addition, photoluminescence was also performed on 1.
创建时间：
2016-02-19
