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Hydroxide-Initiated Conversion of Aromatic Nitriles to Imidazolines: Fullerenes vs TCNE

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NIAID Data Ecosystem2026-03-09 收录
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https://figshare.com/articles/dataset/Hydroxide_Initiated_Conversion_of_Aromatic_Nitriles_to_Imidazolines_Fullerenes_vs_TCNE/2374927
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资源简介:
Transformation of aromatic nitriles to imidazolines has been achieved under basic conditions with the electron-deficient C60 and C70 fullerenes, but not with the electron-deficient olefin of tetracyanoethylene (TCNE). In situ UV–vis–NIR indicates that the ability of RC60– to undergo single-electron transfer (SET) to C60 is crucial for the reaction.
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2016-02-18
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