Hydroxide-Initiated Conversion of Aromatic Nitriles to Imidazolines: Fullerenes vs TCNE
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Transformation of aromatic nitriles to imidazolines has been achieved under basic conditions with the electron-deficient C60 and C70 fullerenes, but not with the electron-deficient olefin of tetracyanoethylene (TCNE). In situ UV–vis–NIR indicates that the ability of RC60– to undergo single-electron transfer (SET) to C60 is crucial for the reaction.
创建时间：
2016-02-18
