Formation of Coordination Porphyrin Pentamers in New Supramolecular Complex of Fullerene: {(ZnTPP)<sub>4</sub>·4-TPyP}·(C<sub>60</sub>)<sub>2</sub>·(C<sub>6</sub>H<sub>5</sub>CN)<sub>3.5</sub>
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A new supramolecular complex of fullerene C60, {(ZnTPP)4·(4-TPyP)}·(C60)2·(C6H5CN)3.5 (ZnTPP: zinc(II) tetraphenylporphyrin; 4-TPyP: tetra(4-pyridyl)porphyrin) involving unusual pentamers containing five porphyrin fragments, was obtained. The crystal structure, IR and UV−vis−NIR spectra of the complex, and the molecular structure of the pentamer are presented.
创建时间：
2016-05-06
