Access to P‑Stereogenic Phosphinates via N‑Heterocyclic Carbene-Catalyzed Desymmetrization of Bisphenols
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下载链接：
https://figshare.com/articles/dataset/Access_to_P_Stereogenic_Phosphinates_via_N_Heterocyclic_Carbene-Catalyzed_Desymmetrization_of_Bisphenols/3427019
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资源简介：
A carbene-catalyzed
desymmetrization of prochiral bisphenol compounds
bearing remote P-stereogenic centers is disclosed. The catalytic reactions
can be performed on gram scales with 1 mol % N-heterocyclic carbene
(NHC) catalyst, providing efficient access to enantiomerically enriched
P-stereogenic phosphinates. The chiral phosphinates prepared with
our method can find widespread applications as asymmetric organic
catalysts and ligands.
创建时间：
2016-06-17
