Synthesis of Iron and Cobalt Complexes of a Ferrocene-Linked Diphosphinoamide Ligand and Characterization of a Weak Iron–Cobalt Interaction
收藏NIAID Data Ecosystem2026-03-09 收录
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资源简介：
A ferrocene-based bis(phosphinoamine) fc(NHPiPr2)2 has been deprotonated and used in salt metathesis reactions to form dimeric complexes ([fc(NPiPr2)2]M)2 (M = Fe, Co). A novel coordination environment for Co(II) is observed including a weak but significant Fe–Co interaction, which was characterized using X-ray crystallography, Mössbauer spectroscopy, and VT-magnetometry. Density functional theory (DFT) calculations including natural bond order analysis provides further support for the interaction and suggests a combination of Fe → Co and Co → Fe interactions.
创建时间：
2016-04-12
