Cu(ClO4)2-Mediated Arene C–H Bond Halogenations of Azacalixaromatics Using Alkali Metal Halides as Halogen Sources
收藏Figshare2016-02-21 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Cu_ClO_sub_4_sub_sub_2_sub_Mediated_Arene_C_H_Bond_Halogenations_of_Azacalixaromatics_Using_Alkali_Metal_Halides_as_Halogen_Sources/2533372
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Regiospecific halogenation of azacalix[1]arene[3]pyridines at the lower rim position of the benzene ring was achieved from their cross-coupling reaction with cost-effective alkali metal halides through the Cu(ClO4)2-mediated aerobic aryl C–H activation, which gave structurally well-defined aryl-Cu(III) intermediates, and a subsequent C–X bond formation reaction under very mild conditions.
创建时间:
2016-02-21



