Enantioselective Selenocyclization via Dynamic Kinetic Resolution of Seleniranium Ions by Hydrogen-Bond Donor Catalysts
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https://figshare.com/articles/dataset/Enantioselective_Selenocyclization_via_Dynamic_Kinetic_Resolution_of_Seleniranium_Ions_by_Hydrogen_Bond_Donor_Catalysts/2044593
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资源简介:
Highly enantioselective selenocyclization
reactions are promoted
by the combination of a new chiral squaramide catalyst, a mineral
acid, and an achiral Lewis base. Mechanistic studies reveal that the
enantioselectivity originates from the dynamic kinetic resolution
of seleniranium ions through anion-binding catalysis.
创建时间:
2015-12-17



