Reaction in well-designed solids allows yielding products with high selectivity and unique compounds that cannot be obtained in solution. However, the precise tuning of the arrangement of reactants in
Coordinative alignment of target small molecules onto a chiral metal–organic framework (MOF-520)provides a powerful method to determine the structures of small molecules through single-crystal X-ray
Reaction in well-designed solids allows yielding products with high selectivity and unique compounds that cannot be obtained in solution. However, the precise tuning of the arrangement of reactants in
The coordination-driven self-assemblies of mixed-ligand dialkyltin derivatives, [(Et2Sn)4 (O2P(OH)Me)2(O3PMe)2(OSO2Et)2·2H2O]n 1, [(Et2Sn)3(O3PMe)2(OSO2Me)2·CHCl3]n 2, and [(Me2Sn)3(O3PBut)2(OSO2Me)2·
Reactions of a saddle-distorted Mo(V)-porphyrin complex, [Mo(DPP)(O)(H2O)]ClO4 (1·ClO4; DPP2− = dodecaphenylporphyrin dianion), with tetra-n-butylammonium (TBA) salts of Keggin-type heteropolyoxomatal
