Organocatalytic Regioselective Concomitant Thiocyanation and Acylation of Oxiranes Using Aroyl Isothiocyanates
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https://figshare.com/articles/dataset/Organocatalytic_Regioselective_Concomitant_Thiocyanation_and_Acylation_of_Oxiranes_Using_Aroyl_Isothiocyanates/4541587
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资源简介：
A regioselective and concomitant
transfer of thiocyanate (−SCN)
and aroyl/acyl (−COR) groups from aroyl/acyl isothiocyanates
onto oxiranes was achieved, giving thiocyanato benzoates in 100% atom
economy. In this biomimetic organocatalytic process, one part (−SCN)
of aroyl/acyl isothiocyanates acts as the nucleophile whereas the
other half (−COR) serves as an electrophilic partner.
创建时间：
2017-01-11
