Enantioselective Synthesis of [6]Carbohelicenes
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https://figshare.com/articles/dataset/Enantioselective_Synthesis_of_6_Carbohelicenes/4579510
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资源简介：
The
use of α-cationic phosphonites derived from TADDOL as
ancillary ligands has allowed a highly regio- and enantioselective
synthesis of substituted [6]carbohelicenes by sequential Au-catalyzed
intramolecular hydroarylation of diynes. Key for these results is
the modular structure of these new ligands, and the enhanced reactivity
that they impart to Au(I)-centers after coordination.
创建时间：
2017-01-23
