Synthesis of 2‑Quinolinones via a Hypervalent Iodine(III)-Mediated Intramolecular Decarboxylative Heck-Type Reaction at Room Temperature
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https://figshare.com/articles/dataset/Synthesis_of_2_Quinolinones_via_a_Hypervalent_Iodine_III_-Mediated_Intramolecular_Decarboxylative_Heck-Type_Reaction_at_Room_Temperature/7427384
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资源简介：
A hypervalent iodine(III)-mediated
intramolecular decarboxylative
Heck-type reaction of 2-vinyl-phenyl oxamic acids has been developed.
The unique ring-strain-enabled radical decarboxylation mechanism is
preliminarily revealed. This protocol features metal-free reaction
conditions and operational simplicity, allowing the lactamization
of 2-vinylanilines using a readily accessible carbonyl source and
the synthesis of various 2-quinolinones with excellent chemoselectivity
at room temperature.
创建时间：
2018-12-07
