In an attempt to prepare the heavier analogue of NHC-stabilized borenium cation, we have prepared a silylene-coordinated borenium equivalent (1a), which can be viewed as a contact ion pair of borenium
Input and output files and XYZ coordinates from driver calculations on the trans-bis(DMSO)tetrachloroiridate anion. The effect of rotation of one DMSO ligand about the Ir–S axis is investigated by DFT
Rhodium and iridium compounds supported by 1-cyclopentadienyl-1,1-bis(4,4-dimethyl-2-oxazolinyl)ethane (MeC(OxMe2)2(C5H4); BoMCp) form the 18-electron piano-stool compounds {BoMCp}ML2 (L = C2H4, C
Oxidations of a trigonal-bipyramidal, high-spin Ni(II) dithiolate complex of a pentadentate, N3S2-donor ligand, N1,N9-bis(imino-2-mercaptopropane)-1,5,9-triazanonane) nickel(II), and the structurally