Cyclometalated Palladium(II) Fragments as Building Blocks in the Construction of New Heteronuclear Metalomacrocycles
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https://figshare.com/articles/dataset/Cyclometalated_Palladium_II_Fragments_as_Building_Blocks_in_the_Construction_of_New_Heteronuclear_Metalomacrocycles/3764484
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资源简介：
The complexes [{(X)PdN(Cy)C(H)C6H2C(H)N(Cy)Pd(X)}2{(μ-Ph2PC5H4FeC5H4PPh2}2]
(X = Cl (3), X = Br (4)) have been prepared by reaction of [(X)PdN(Cy)C(H)C6H2C(H)N(Cy)Pd(X)]n (X = Cl (1), X = Br (2)) with 1,1‘-bis(diphenylphosphino)ferrocene (dppf), and
they were characterized by elemental analysis (C, H, N) and by 1H and 31P{1H} NMR
spectroscopy in CDCl3. The compounds are arranged as hexanuclear supramolecular cages
containing two different metals, palladium and iron. The crystal structure of complex 4 was
determined by X-ray diffraction studies.
创建时间：
2016-08-26
