Nickel(IV)-Catalyzed C–H Trifluoromethylation of (Hetero)arenes
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https://figshare.com/articles/dataset/Nickel_IV_-Catalyzed_C_H_Trifluoromethylation_of_Hetero_arenes/9239564
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资源简介：
This
Article describes the development of a stable NiIV complex
that mediates C(sp2)–H trifluoromethylation
reactions. This reactivity is first demonstrated stoichiometrically
and then successfully translated to a NiIV-catalyzed C–H
trifluoromethylation of electron-rich arene and heteroarene
substrates. Both experimental and computational mechanistic studies
support a radical chain pathway involving NiIV, NiIII, and NiII intermediates.
创建时间：
2019-08-02
