Role of London Dispersion Interactions in Ga-Substituted Dipnictenes
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https://figshare.com/articles/dataset/Role_of_London_Dispersion_Interactions_in_Ga-Substituted_Dipnictenes/7905251
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资源简介：
We report the synthesis
and structural characterization of Ga-substituted
diarsene [L(EtO)GaAs]2, which is an exemplary case of a
Ga-substituted dipnictene of the general type [L(X)Ga]2E2 (L = C[C(Me)N(2,6-i-Pr2-C6H3)]2, X = F, Cl, Br, I, NMe2, OEt; E = As, Sb, Bi). We examined this extended series of
compounds computationally and found that attractive London dispersion
interactions between the substituents on the N,N′-chelating
β-diketiminate ligands as well as pnictogen−π interactions
between the group 15 metal center and the ligand are key factors for
the stability and the electronic structures of such types of complexes.
创建时间：
2019-03-27
