Synthesis and Spectroscopic Characterization of High-Spin Mononuclear Iron(II) p‑Semiquinonate Complexes
收藏Figshare2015-12-17 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_and_Spectroscopic_Characterization_of_High_Spin_Mononuclear_Iron_II_i_p_i_Semiquinonate_Complexes/2044614
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资源简介：
Two mononuclear iron(II) p-semiquinonate (pSQ) complexes have been generated via one-electron reduction of precursor complexes containing a substituted 1,4-naphthoquinone ligand. Detailed spectroscopic and computational analysis confirmed the presence of a coordinated pSQ radical ferromagnetically coupled to the high-spin FeII center. The complexes are intended to model electronic interactions between (semi)quinone and iron cofactors in biology.
创建时间：
2015-12-17
