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New Routes to High Nuclearity Clusters: Fluoride-Based Octametallic and Tridecametallic Clusters of Manganese

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/New_Routes_to_High_Nuclearity_Clusters_Fluoride_Based_Octametallic_and_Tridecametallic_Clusters_of_Manganese/3360712
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The reaction of MnF3 with 5,6-dimethylbenzotriazole (Me2BTAH) gives the [MnIII8] complex [Mn8O4(OMe)2(Me2BTA)6F8(Me2BTAH)(MeOH)8] and the [MnIV3MnIII10] complex [Mn13O12(Me2BTA)12F6(MeOH)10(H2O)2]. The octametallic species is an “intermediate” in the formation of the tridecametallic cluster.
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2003-11-03
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