Double-Concave Binding of Bicorannulenyl Dianion: Cesium vs Lithium Salts
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https://figshare.com/articles/dataset/Double_Concave_Binding_of_Bicorannulenyl_Dianion_Cesium_vs_Lithium_Salts/2285089
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资源简介：
The
first X-ray structural characterization of bicorannulenyl dianion
has been accomplished for two alkali metal salts, [Li+(THF)4]2[C40H182–] (1) and [Cs+(18-crown-6)]2[C40H182–] (2). This
crystallographic study revealed the biaryl stereochemistry, geometry
transformation upon acquiring two electrons, and different binding
preferences of Li+ vs Cs+ ions in the solid-state
products.
创建时间：
2014-06-09
