Boraphosphaalkene Synthesis via Phosphaalkyne Insertion into 9‑Borafluorene
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The reaction of 1-adamantylphosphaalkyne with 9-phenyl-9-borafluorene resulted in the insertion of the PC unit into the endocyclic B–C bond, generating a seven-membered 1,3-boraphosphaalkene. The mechanism was investigated computationally, indicating that the reaction proceeds via a bond metathesis pathway.
创建时间：
2018-05-22
