Amidine Dications: Isolation and [Fe]-Hydrogenase-Related Hydrogenation

NIAID Data Ecosystem2026-03-09 收录

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Amidine Dications: Isolation and [Fe]-Hydrogenase-Related Hydrogenation

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2015-12-16

Tantalum Alkyl and Silyl Complexes of the Bulky (Terphenyl)imido Ligand [2,6-(2,4,6-Me 3 C 6 H 2 ) 2 C 6 H 3 N] 2- ([Ar*N] 2- ). Generation and Reactivity of [(Ar*N)(Ar*NH)Ta(H)(OSO 2 CF 3 )], Which Reversibly Transfers Hydride to an Aromatic Ring of the Arylamide Ligand

金属有机催化

氢化反应

Tantalum complexes containing the sterically demanding imido ligand [2,6-(2,4,6-Me3C6H2)2C6H3N]2- ([Ar*N]2-) are reported. The dimethyl complex (Ar*N)(Ar*NH)TaMe2 (4), prepared by the reaction of 2

NIAID Data Ecosystem60

Domino C–H Activation/Directing Group Migration/Alkyne Annulation: Unique Selectivity by d6‑Cobalt(III) Catalysts

金属有机催化

C–H键活化反应机理

Distinct selectivity control in Cp*CoIII-catalyzed domino C–H activation/pyridine directing group migration/alkyne annulation has been accomplished through the nucleophilicity of an organometallic cob

Figshare2020-03-16 更新10

1,6-Carbene Transfer: Gold-Catalyzed Oxidative Diyne Cyclizations

金属有机催化

有机合成方法

In the presence of a gold catalyst an unprecedented oxidative cyclization of diynes takes place. The reaction cascade is initiated by an oxygen transfer from a N-oxide onto a gold-activated alkyne. Th

Figshare2016-02-18 更新00

Tetrabenzo[ a,c,g,i ]fluorenyllithium and η 5 -Tetrabenzo[ a,c,g,i ]fluorenyltitanium Complexes

金属有机催化

乙烯聚合

Tetrabenzo[a,c,g,i]fluorene (Tbf-H, 4) was deprotonated with n-butyllithium, leading to ionic Tbf-LiLn complexes 5 and 6, consisting of well-separated cations (Li(THF)4 (5), Li(DME)3 (6)) and Tbf anio

NIAID Data Ecosystem50

Reaction of Dinuclear Rhodium 4,5-Diazafluorenyl-9-Carboxylate Complexes with H2 and CO2

金属有机催化

二氧化碳还原反应机理

The reactivity of the dinuclear Rh(I) 4,5-diazafluorenyl-9-carboxylate complex 4 with H2 was explored in an attempt to reduce the trapped CO2-derived moiety. After overnight reaction with H2 the only

Figshare2016-02-17 更新10

Amidine Dications: Isolation and [Fe]-Hydrogenase-Related Hydrogenation

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