Reactivity of Phosphasilametallacyclopropane toward Substrates with Polarized E−H Bonds (E = O, N, S, and P): Formation and Structures of Ring-Opening Products
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/Reactivity_of_Phosphasilametallacyclopropane_toward_Substrates_with_Polarized_E_H_Bonds_E_O_N_S_and_P_Formation_and_Structures_of_Ring_Opening_Products/3301321
下载链接
链接失效反馈官方服务：
资源简介：
Treatment of a three-membered metallacycle Cp*(CO)Fe{κ2(Si,P)-SiMe2PPh2} (1) with
substrates of the type RnEH (ERn = OH, OMe, OtBu, OPh, SpTol, NEt2, NPhH, PPh2, and
PPhH) results in the instantaneous formation of the ring-opening products Cp*(CO)Fe(PPh2H)(SiMe2ERn). In these reactions, 1,2-addition of the substrates occurs exclusively across
the silicon−phosphorus bond in 1. The structures of the products have been unequivocally
determined by spectroscopic data and X-ray diffraction analysis.
创建时间：
2005-02-14
