Proton-Induced Dynamic Equilibrium between Cyclometalated Ruthenium rNHC (Remote N-Heterocyclic Carbene) Tautomers with an NAD+/NADH Function
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Proton_Induced_Dynamic_Equilibrium_between_Cyclometalated_Ruthenium_rNHC_Remote_N_Heterocyclic_Carbene_Tautomers_with_an_NAD_sup_sup_NADH_Function/2640493
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资源简介：
Cyclometalated ruthenium(II) complexes having acridine moieties have been synthesized and characterized by spectroscopic methods. Protonation of the acridine nitrogen of the ruthenium(II) complexes not only causes dynamic equilibrium with remote N-heterocyclic carbene RuC complexes but also generates the NAD+/NADH redox function driven by a proton-coupled two-electron transfer accompanying a reversible C–H bond formation in the pyridinium ring.
创建时间：
2016-02-23
