Discovering Copper for Methane C–H Bond Functionalization
收藏NIAID Data Ecosystem2026-03-08 收录
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https://figshare.com/articles/dataset/Discovering_Copper_for_Methane_C_H_Bond_Functionalization/2205958
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资源简介：
The copper complex Tp(CF3)2,BrCu(NCMe) (1, Tp(CF3)2,Br = hydrotris((3,5-bis(trifluoromethyl)-4-bromo)-pyrazol-1-yl)borate)
catalyzes the insertion of the CHCO2Et group (from ethyl
diazoacetate N2CHCO2Et, EDA) into the C–H
bonds of methane, in a homogeneous process that uses supercritical
carbon dioxide (scCO2) as the reaction medium. Other light
alkanes such as ethane, propane, and butane have been also functionalized
with this copper-based catalyst, in the first example of the derivatization
of the series of C1–C4 alkanes with this
metal and a soluble catalyst.
创建时间：
2016-02-15
