Reagent-Dependent Formation of C−C and C−F Bonds in Pt Complexes: An Unexpected Twist in the Electrophilic Fluorination Chemistry
收藏NIAID Data Ecosystem2026-03-06 收录
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Cyclometalated platinum(II) complexes (C−P)Pt(Aryl)py undergo oxidative addition reaction upon treatment with electrophilic fluorination reagents, XeF2 or N-fluoro-2,4,6-trimethylpyridinium tetrafluoroborate, giving eventually products of C−C coupling. However, when aryl = mesityl, the two reagents give completely different products: the N−F salt still favors the C−C coupling reaction while XeF2 gives the unprecedented benzylic fluorination of one of the ortho-methyl groups of the mesityl ligand.
创建时间：
2016-02-24
