Catalytic Asymmetric Synthesis of Chiral 2‑Vinylindole Scaffolds by Friedel–Crafts Reaction
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https://figshare.com/articles/dataset/Catalytic_Asymmetric_Synthesis_of_Chiral_2_Vinylindole_Scaffolds_by_Friedel_Crafts_Reaction/4595974
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资源简介:
A chiral bis(imidazolidine)pyridine
(PyBidine)–Ni(OTf)2 complex smoothly catalyzed an
asymmetric Friedel–Crafts
reaction of 2-vinylindoles with nitroalkenes to give chiral indoles
in a highly enantioselective manner while maintaining the 2-vinyl
functionality. The chiral 2-vinylindoles offer unique chiral scaffolds
for diverse transformations.
创建时间:
2017-01-30



