Catalytic Asymmetric Synthesis of Chiral 2‑Vinylindole Scaffolds by Friedel–Crafts Reaction
收藏NIAID Data Ecosystem2026-03-10 收录
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A chiral bis(imidazolidine)pyridine (PyBidine)–Ni(OTf)2 complex smoothly catalyzed an asymmetric Friedel–Crafts reaction of 2-vinylindoles with nitroalkenes to give chiral indoles in a highly enantioselective manner while maintaining the 2-vinyl functionality. The chiral 2-vinylindoles offer unique chiral scaffolds for diverse transformations.
创建时间：
2017-01-30
