Iron-Catalyzed Radical Intermolecular Addition of Unbiased Alkenes to Aldehydes
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https://figshare.com/articles/dataset/Iron-Catalyzed_Radical_Intermolecular_Addition_of_Unbiased_Alkenes_to_Aldehydes/13053955
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资源简介：
The
intermolecular reductive radical coupling of aldehydes with
nonactivated alkenes, employing metal hydride atom transfer (MHAT)
catalysis with a combination of FeII and FeIII salts, is described. This constitutes the first use of aldehydes
as viable acceptor groups in MHAT reactions. The insights gained in
this study led to the reexamination of the previously reported intramolecular
version of the reaction, and the addition of FeII salts
allowed the development of a more efficient second-generation approach.
创建时间：
2020-10-05
