Phosphine-Mediated Stereoselective Reductive Cyclopropanation of α-Substituted Allenoates with Aromatic Aldehydes
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https://figshare.com/articles/dataset/Phosphine_Mediated_Stereoselective_Reductive_Cyclopropanation_of_Substituted_Allenoates_with_Aromatic_Aldehydes/2794282
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资源简介:
A novel phosphine-mediated reductive cyclopropanation between α-substituted allenoates 2 and aldehydes 1 is described. It represents a new member of the allene-based annulations, which provides facile and efficient access to highly functionalized cyclopropanes 3 from simple and readily available starting materials. It also unveils an unprecedented reactivity pattern of allenoates with aldehydes.
创建时间:
2010-02-05



