An Unusual Three-Dimensional Water Cluster in Metal−Organic Frameworks Based on ZnX<sub>2</sub> (X = ClO<sub>4</sub>, BF<sub>4</sub>) and an Azo-Functional Ligand
收藏NIAID Data Ecosystem2026-03-06 收录
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A highly symmetrical three-dimensional (3D) water network containing cage-shaped tetradecameric water cluster units (H2O)14 is observed in the crystalline 3D metal−organic framework materials 1 and 2. This is a rare demonstration of a 3D water clathrate network trapped in a cavity of a 3D metal−organic framework, and there are no classical hydrogen bonding interactions within the skeleton of the metal−organic framework.
创建时间：
2016-02-25
