{Fe(3CNpy)<sub>2</sub>[Cu(3CNpy)(μ-CN)<sub>2</sub>]<sub>2</sub>}: a One-Dimensional Cyanide-Based Spin-Crossover Coordination Polymer
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资源简介：
A novel one-dimensional coordination polymer made up of FeII, 3-cyanopyridine (3CNpy), and the singular in situ formed [CuI(3CNpy)(CN)2]- anionic bridge has been synthesized. This compound undergoes a spin-crossover behavior according to its magnetic and calorimetric properties. The crystal structure of the title compound has been studied in the high- and low-spin states and correlated with the character of the spin conversion. Evidence for intense spin-state-dependent Cu····Cu interactions between the chains is also reported.
创建时间：
2016-03-01
