Mercury(II) Triflate-Catalyzed Cycloisomerization of Allenynes to Allenenes
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https://figshare.com/articles/dataset/Mercury_II_Triflate_Catalyzed_Cycloisomerization_of_Allenynes_to_Allenenes/2969965
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资源简介:
Cycloisomerizations of allenynes to allenenes have been
studied in the presence of catalytic amounts of [Hg(OTf)2]
in acetonitrile. The catalytic system is quite effective for
terminal 1,6-allenynes: allenenes were obtained in reasonable
to high yields. However, treatment of allenynes with disubstituents at the allenic terminal carbon yielded a triene and/or allenene as a major product(s) depending upon the
substituents.
创建时间:
2016-06-03



