Widely Applicable Metallacarborane Reagents for π‑Conjugated Systems
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https://figshare.com/articles/dataset/Widely_Applicable_Metallacarborane_Reagents_for_Conjugated_Systems/2287441
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资源简介：
The compounds [N(CH3)4][3,3′-Co(8-(p-C6H4C2H3)-1,2-C2B9H10)(1′,2′-C2B9H11)], [N(CH3)4][3,3′-Co(8-(p-C6H4CHO)-1,2-C2B9H10)(1′,2′-C2B9H11)], and [N(CH3)4][3,3′-Co(8-(m-C6H4CHO)-1,2-C2B9H10)(1′,2′-C2B9H11)] were synthesized using an easy methodology, in very
good yields and large quantities, which are important requisites to
be employed as starting reagents. They have been fully characterized
by elemental analysis, IR, NMR, and MALDI-TOF-MS, and the crystal
structures of [N(CH3)4][3,3′-Co(8-(p-C6H4C2H3)-1,2-C2B9H10)(1′,2′-C2B9H11)] and [N(CH3)4][3,3′-Co(8-(p-C6H4CHO)-1,2-C2B9H10)(1′,2′-C2B9H11)] were elucidated by single-crystal X-ray diffraction.
These compounds, having terminal formyl and vinyl functional groups,
are suitable platforms to involve the aromatic cobaltabisdicarbollide
unit into extended π-conjugated systems. It is expected that
these synthons will facilitate the applicability of metallacarboranes
in a wide variety of different fields, where π-conjugated systems
are needed to keep electronic communication.
创建时间：
2014-06-02
