Enantioselective 1,4-Addition of Unmodified Ketone Catalyzed by a Bimetallic Zn−Zn-Linked−BINOL Complex
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https://figshare.com/articles/dataset/Enantioselective_1_4-Addition_of_Unmodified_Ketone_Catalyzed_by_a_Bimetallic_Zn_Zn-Linked_BINOL_Complex/3741138
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资源简介：
1,4-Addition (Michael addition) of 2-hydroxy-2‘-methoxyacetophenone (2) to various α,β-unsaturated ketones was efficiently promoted by a
bimetallic Zn−Zn-linked−BINOL complex 3 with good yield (up to 90%) and excellent enantiomeric excess (up to 99% ee). The resulting
2-hydroxy-1,5-diketones were successfully converted to synthetically more versatile esters and amides.
创建时间：
2016-08-20
