Metal-Organic Framework from an Anthracene Derivative Containing Nanoscopic Cages Exhibiting High Methane Uptake
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https://figshare.com/articles/dataset/Metal_Organic_Framework_from_an_Anthracene_Derivative_Containing_Nanoscopic_Cages_Exhibiting_High_Methane_Uptake/2961532
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资源简介：
A microporous metal-organic framework, PCN-14, based on an anthracene derivative, 5,5‘-(9,10-anthracenediyl)di-isophthalate (H4adip), was synthesized under solvothermal reaction conditions. X-ray
single crystal analysis revealed that PCN-14 consists of nanoscopic cages suitable for gas storage.
N2-adsorption studies of PCN-14 at 77 K reveal a Langmuir surface area of 2176 m2/g and a pore volume
of 0.87 cm3/g. Methane adsorption studies at 290 K and 35 bar show that PCN-14 exhibits an absolute
methane-adsorption capacity of 230 v/v, 28% higher than the DOE target (180 v/v) for methane storage.
创建时间：
2016-06-03
