Enantioselective Diels–Alder Reaction of α-(Acylthio)acroleins: A New Entry to Sulfur-Containing Chiral Quaternary Carbons
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https://figshare.com/articles/dataset/Enantioselective_Diels_Alder_Reaction_of_Acylthio_acroleins_A_New_Entry_to_Sulfur_Containing_Chiral_Quaternary_Carbons/2513392
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资源简介：
A catalytic and enantioselective Diels–Alder reaction of α-(carbamoylthio)acroleins induced by an organoammonium salt of chiral triamine is described. α-(Carbamoylthio)acroleins are designed and synthesized as new sulfur-containing dienophiles for the first time. The Diels–Alder reaction affords chiral tertiary thiol precursors with up to 91% ee.
创建时间：
2012-06-15
