Slow Magnetic Relaxation in a Lanthanide-[1]Metallocenophane Complex
收藏Figshare2017-06-12 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Slow_Magnetic_Relaxation_in_a_Lanthanide-_1_Metallocenophane_Complex/5101138
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The first example of a lanthanide metallocenophane complex has been isolated as [Li(THF)4][DyFc3Li2(THF)2] (1). The molecular structure of complex 1 differs dramatically from those of main group and transition metal ferrocenophane complexes and features a distorted trigonal prismatic geometry around the Dy(III) ion and close intramolecular Dy···Fe distances. Furthermore, complex 1 exhibits all characteristics of a soft single-molecule magnet.
创建时间：
2017-06-12
