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Ru–OSO Coordination Photogenerated at 100 K in Tetraammineaqua(sulfur dioxide)ruthenium(II) (±)-Camphorsulfonate

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Figshare2016-02-22 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Ru_OSO_Coordination_Photogenerated_at_100_K_in_Tetraammineaqua_sulfur_dioxide_ruthenium_II_Camphorsulfonate/2553208
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The photoinduced O-bound coordination mode in RuSO2 complexes, previously observed only at 13 K, has been generated at 100 K in tetraammineaqua­(sulfur dioxide)­ruthenium­(II) (±)-camphorsulfonate. This coordination state, often denoted MS1, decays to the η2-bound MS2 state, with an estimated half-life of 3.4(8) h and a long-lived population of 2.9(4)% at 120 K.
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2016-02-22
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