Lithium Aluminates on a Molecular Titanium Oxide
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下载链接:
https://figshare.com/articles/dataset/Lithium_Aluminates_on_a_Molecular_Titanium_Oxide/2575618
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资源简介:
Lithium aluminates Li[Al(O-2,6-Me2C6H3)R′3] (R′ = Et, Ph) react with
the
μ3-alkylidyne oxoderivative ligands [{Ti(η5-C5Me5)(μ-O)}3(μ3-CR)] [R = H (1), Me (2)] to afford
the aluminum–lithium–titanium cubane complexes [{R′3Al(μ-O-2,6-Me2C6H3)Li}(μ3-O)3{Ti(η5-C5Me5)}3(μ3-CR)] [R =
H, R′ = Et (5), Ph (7); R = Me, R′
= Et (6), Ph (8)]. Complex 7 evolves with the formation of a lithium dicubane species and a Li{Al(μ-O-2,6-Me2C6H3)Ph3}2] unit.
创建时间:
2016-02-22



