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New Chromium(III) Complexes as Highly Active Catalysts for Olefin Polymerization

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https://figshare.com/articles/dataset/New_Chromium_III_Complexes_as_Highly_Active_Catalysts_for_Olefin_Polymerization/3767439
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Cyclopentadienyl ligands functionalized by quinoline or N,N-dimethylaniline have an ideal and rigid geometry for the formation of half-sandwich compounds. As a result, stable chromium(III) complexes 5−8 with intramolecular nitrogen coordination have been obtained. Treatment with MAO leads to highly active, temperature-stable catalysts for the polymerization of ethylene.
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2016-08-26
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