Chemoselective Hydrogenation of Carbonyl Compounds and Acceptorless Dehydrogenative Coupling of Alcohols
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https://figshare.com/articles/dataset/Chemoselective_Hydrogenation_of_Carbonyl_Compounds_and_Acceptorless_Dehydrogenative_Coupling_of_Alcohols/2182900
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资源简介：
OsHCl(CO)[κ3-PyCH2NHC2H4NHPtBu2] is the first efficient
catalyst for chemoselective reduction of challenging unsaturated esters
to enols and for acceptorless coupling of amines with MeOH and EtOH
affording formamides and acetamides. The NMR, ESI-MS, and DFT data
indicate a mechanism proceeding in the metal coordination sphere and
producing no free organic intermediates.
创建时间：
2016-02-14
