Identification of the Formal +2 Oxidation State of Neptunium: Synthesis and Structural Characterization of {NpII[C5H3(SiMe3)2]3}1–
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https://figshare.com/articles/dataset/Identification_of_the_Formal_2_Oxidation_State_of_Neptunium_Synthesis_and_Structural_Characterization_of_Np_sup_II_sup_C_sub_5_sub_H_sub_3_sub_SiMe_sub_3_sub_sub_2_sub_sub_3_sub_sup_1_sup_/6447692
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We report a new formal oxidation state for neptunium in a crystallographically characterizable molecular complex, namely Np2+ in [K(crypt)][NpIICp″3] [crypt = 2.2.2-cryptand, Cp″ = C5H3(SiMe3)2]. Density functional theory calculations indicate that the ground state electronic configuration of the Np2+ ion in the complex is 5f46d1.
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2018-06-05
