Oxidative Addition Reactions of Bis-Aminophosphine and Bis-Phosphinite Nickel(0) Pincer Complexes
收藏NIAID Data Ecosystem2026-03-09 收录
下载链接：
https://figshare.com/articles/dataset/Oxidative_Addition_Reactions_of_Bis_Aminophosphine_and_Bis_Phosphinite_Nickel_0_Pincer_Complexes/2541793
下载链接
链接失效反馈官方服务：
资源简介：
The tridentate ligands S(CH2CH2NHPiPr2)2 and S(CH2CH2OPiPr2)2 undergo
C–S
oxidative addition to give (SCH2CH2EPiPr2)Ni(CH2CH2EPiPr2) (E = NH (2), O (4)). The corresponding reaction of the aminophosphine ligand HN(CH2CH2NHPiPr2)2 is reversible, affording access to a transient Ni(0) synthon that
undergoes oxidative addition with HCl, MeI, or o-ClC6H4F to give the Ni(II) complexes [HN(CH2CH2NHPiPr2)2NiR]X
(R = H, X = Cl (7), PF6 (8);
R = Me, X = I (9); R = o-C6H4F, X = Cl (10)). These observations are
supported via computations.
创建时间：
2016-02-21
