Raw data for new compounds described in the paper: "Enantioselective nickel-catalyzed arylative intramolecular 1,4-allylations"
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Raw data for new compounds described in the paper: "Enantioselective nickel-catalyzed arylative intramolecular 1,4-allylations" The enantioselective nickel-catalyzed desymmetrization of allenyl cyclohexa-2,5-dienones by reaction with arylboronic acids is described. Nickel-catalyzed arylation of the allene gives allylnickel species, which undergo cyclization by 1,4-allylation to produce hexahydroindol-5-ones and hexahydrofuran-5-ones with three contiguous stereocenters in high diastereo- and enantioselectivities.
提供机构：
Royal Society of Chemistry
创建时间：
2018-05-15
