Stoichiometric Carbon–Carbon Bond Forming Reaction of 1,3-Diene with 1,2-Diene in a Ruthenium(0) Complex
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https://figshare.com/articles/dataset/Stoichiometric_Carbon_Carbon_Bond_Forming_Reaction_of_1_3_Diene_with_1_2_Diene_in_a_Ruthenium_0_Complex/2506858
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资源简介：
A stoichiometric reaction of Ru(η4-cisoid-2,3-dimethyl-1,3-butadiene)(η4-1,5-COD)(NCMe)
(1a) with ethyl 2,3-butadienoate produces rac-prone,supine-(1S,2R,4S,5R)-1-anti-4-anti-Ru(η3:η3-1-ethoxycarbonyl-2-methylidene-4,5-dimethylhex-4-ene-1,6-diyl)(η4-1,5-COD) (2aa) in 90% yield and in 52% isolated
yield. The stereochemistry of this and the related products shows
prior coordination of the 1,2-diene followed by the nucleophilic attack
of the coordinated 1,3-diene, where the Ru(0) complex distinguishes
two different orthogonal π planes and the prostereogenic face,
depending on the steric congestion, regardless of their electronic
properties.
创建时间：
2016-02-20
