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Insertion and Substitution Chemistry at the Boron Fourth Position in Charge-Neutral Zwitterionic Tripodal Tris(methimazolyl)borate Ligands

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https://figshare.com/articles/dataset/Insertion_and_Substitution_Chemistry_at_the_Boron_Fourth_Position_in_Charge_Neutral_Zwitterionic_Tripodal_Tris_methimazolyl_borate_Ligands/2539105
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A number of new charge-neutral zwitterionic tris­(methimazolyl)­borate ligands have been synthesized, either by substitution of the dimethylamine group in the adduct (dimethylamine)­tris­(methimazolyl)­borane (1) or by insertion into its B–N­(dimethylamine) bond by an unsaturated Lewis base. Two new anionic ligands, (thiocyanato)­tris­(methimazolyl)­borate and (cyano)­tris­(methimazolyl)­borate, have also been accessed by this method.
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2012-03-19
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