Insertion and Substitution Chemistry at the Boron Fourth Position in Charge-Neutral Zwitterionic Tripodal Tris(methimazolyl)borate Ligands
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https://figshare.com/articles/dataset/Insertion_and_Substitution_Chemistry_at_the_Boron_Fourth_Position_in_Charge_Neutral_Zwitterionic_Tripodal_Tris_methimazolyl_borate_Ligands/2539105
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资源简介:
A number of new charge-neutral zwitterionic tris(methimazolyl)borate
ligands have been synthesized, either by substitution of the dimethylamine
group in the adduct (dimethylamine)tris(methimazolyl)borane (1) or by insertion into its B–N(dimethylamine) bond
by an unsaturated Lewis base. Two new anionic ligands, (thiocyanato)tris(methimazolyl)borate
and (cyano)tris(methimazolyl)borate, have also been accessed by this
method.
创建时间:
2012-03-19



