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Porphyrin Supermolecules: Synthesis and Self-Assembly Features of Zinc-5-(3‘-pyridyl)-10,15,20-tris(4‘-hydroxyphenyl)porphyrin

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https://figshare.com/articles/dataset/Porphyrin_Supermolecules_Synthesis_and_Self_Assembly_Features_of_Zinc_5_3_pyridyl_10_15_20_tris_4_hydroxyphenyl_porphyrin/3374512
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Targeted synthesis of the title compound, with one converging coordination site and three diverging H-bonding sites, has led to the formation of multiporphyrin oligomers by directed intermolecular coordination, without resorting to external auxiliaries. A uniquely structured cyclic tetraporphyrin supermolecule was detected in solution, isolated in the solid state, and characterized in detail by X-ray diffraction.
创建时间:
2016-05-12
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